Quantum chemical study on asymmetric allylation of benzaldehyde in the presence of chiral allylboronate.
نویسندگان
چکیده
The quantum chemical method is employed to study the modified asymmetric allylation of benzaldehyde controlled by diisopropyl D-(-)-tartrate auxiliary. All the structures are optimized completely at the B3LYP/6-31G(d,p) level. The (R)-secondary alcohol can be achieved mainly through a six-membered ring chair-like transition state structure. From the relative reaction rates theory the main product configuration predicted is in agreement with the experiment result.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of Zhejiang University. Science. B
دوره 6 6 شماره
صفحات -
تاریخ انتشار 2005